ShipCalculators.com

Chlorinity

D1. Physical and chemical oceanography and marine meteorology

Definition

Mass of chloride per kilogram of seawater, historically used to estimate salinity.

Chlorinity is the mass in grams of chloride-equivalent halides (chloride, bromide, iodide expressed as chloride) per kilogram of seawater, measured historically by silver-nitrate titration. It was the practical basis for salinity before conductivity methods, tied to it by the UNESCO 1967 relation S = 1.80655 x Cl. That coefficient was chosen so the new scale matched the older Knudsen formula at a salinity of 35. Chlorinity works because the major-ion ratios of seawater are nearly constant, the principle of constant proportions, so one ion concentration fixes total salt content. Practical Salinity and Absolute Salinity under TEOS-10 have since superseded it.

Source: UNESCO (1967) chlorinity-salinity relation; Knudsen tables